Chapter 7 · Macromolecules

Building, Breaking and Carbohydrates

Relate monomers to polymers, choose the right reaction for building or breaking, and classify sugars by size and job.

11 min read

Monomers and polymers

Think of language. Monomers are letters, polymers are words, and biomolecules are sentences. A monomer is a small unit, and many monomers link to make a polymer. Every living cell has thousands of different kinds of polymers.

Two reactions, one water molecule

Dehydration builds: water comes out++H₂OHydrolysis breaks: water goes in+H₂O+
Dehydration buildsHydrolysis breaks
Joins a monomer to the chain
Splits a bond in the polymer
A water molecule comes OUT
A water molecule goes IN
De = remove, hydration = water
Hydro = water, lysis = break
Makes disaccharides, starch, polypeptides
Happens in digestion

Worked example

Counting water

A cell links 5 glucose monomers into one straight chain. How many water molecules are released?

  1. Sketch 5 circles in a row. Count the links between neighbors: 4.

  2. Every link is one dehydration reaction, and each one releases one water.

  3. So 4 bonds means 4 waters. The rule: waters = bonds = monomers − 1.

Answer

4 water molecules. Breaking the same chain back into 5 monomers would use 4 waters.

Quick check

Saliva turns a cracker's starch into smaller sugars while you chew. Which reaction is this?

Carbohydrates

Sugars have a fixed ratio of 1 carbon : 2 hydrogen : 1 oxygen and a carbon skeleton that often forms a ring. Glucose, C₆H₁₂O₆, shows the ratio. They come in three sizes.

TypeSizeExamples
Monosaccharide
1 sugar unit
Glucose, fructose, galactose, ribose
Disaccharide
2 linked units
Sucrose (glucose + fructose), lactose (galactose + glucose), maltose (glucose + glucose)
Polysaccharide
Many units
Starch, glycogen, cellulose

Glucose is the main fuel for cellular work. Cells break it down and pull out the stored energy.

Three polysaccharides, one monomer

Starch (plants): coiled stockpileGlycogen (animals): highly branched stockpileCellulose (plants): straight building material
StarchGlycogenCellulose
Plant cells
Animal cells
Plant cells
Sugar stockpile
Sugar stockpile in liver and muscle
Building material: protection, stiffness
Chains coil up like phone cords
Highly branched
Straight chains
Humans digest it
Humans make and use it
Humans cannot digest it (fiber)

Key concept

Same letters, different words

All three are made of glucose monomers. The way the units are linked and arranged gives each one a different job, and it decides whether your enzymes can take it apart.

Carbohydrates and water

All carbohydrates are hydrophilic because of their hydroxyl groups. Mono- and disaccharides dissolve easily. Cellulose absorbs water well but does not really dissolve. Attracting water and dissolving are not the same thing.